Welcome to Smogon! Take a moment to read the Introduction to Smogon for a run-down on everything Smogon, and make sure you take some time to read the global rules.
I'm GMT-5 and I can play Monday and Wednesday from 1:30 PM to 3:30 PM and after 6 PM everyday. If we play on the weekend, I should be free after 2 or 3 PM until 10 PM