Welcome to Smogon! Take a moment to read the Introduction to Smogon for a run-down on everything Smogon, and make sure you take some time to read the global rules.
I'm GMT-5 and I'm free starting at this time tomorrow. I can play pretty much every day after 6 PM and/or earlier on Saturday/Sunday. I also got Wednesday morning around 7 and 8 AM and I can move things around in my schedule if necessary.